Question

Нужна с органической химии

Answer 1

298314.

1) C6H5-C(O)OEt + KOH = C6H5-COOK + EtOH;

2) C6H5-COOK + HCl = C6H5COOH + KCl;

3) C6H5COOH + SOCl2 = C6H5C(O)Cl + SO2 + HCl;

4) C6H5C(O)Cl + C2H5NH2 (C5H5N) = C6H5C(O)-NH-C2H5 + HCl;

5) 2C6H5C(O)-NH-C2H5 + LiAlH4 (ТГФ) = 2C6H5-CH2-NH-C2H5 + LiAlO2;

298325.

Для получения гомолога карбоновой к-ты исп. р-ию Арндта-Эйстерта:

1) H3C-COOH + SOCl2 = H3CC(O)Cl + SO2 + HCl;

2) H3CC(O)Cl + 2CH2N2 (диазометан) (C6H6/(C2H5)2O - р-ль) = H3CC(O)CHN2 + CH3Cl + N2;

3) H3CC(O)CHN2 + H2O (Ag2O) = H3CCH2COOH + N2;

299075.

1) 3H3C-C(CH3)2-OH + PBr3 = 3H3C-C(CH3)2-Br + H3PO3;

2) H3C-C(CH3)2-Br + Mg (безв. (C2H5)2O) =

H3C-C(CH3)2-MgBr;

3) H3C-C(O)-CH3 + Br2 (HCl, H2O2) = H3C-C(O)-CH2Br + HBr;

4) H3C-C(O)-CH2Br + HO-(CH2)2-OH (H+) =

H3C-C((CH2O)2)-CH2Br + H2O;

5) H3C-C(CH3)2-MgBr + H3C-C((CH2O)2)-CH2Br (безв. (C2H5)2O) = H3C-C(CH3)2-CH2-C((CH2O)2)-CH3 + MgBr2;

6) H3C-C(CH3)2-CH2-C((CH2O)2)-CH3 + H2O (H+) =

H3C-C(CH3)2-CH2-C(O)-CH3 + HO-(CH2)2-OH;

7) H3C-C(CH3)2-CH2-C(O)-CH3 + 3I2 + 4NaOH (20 C, H2O+диоксан) =

H3C-C(CH3)2-CH2-COONa + 3NaI + CHI3 + 3H2O;

8) H3C-C(CH3)2-CH2-COONa + EtCl =

H3C-C(CH3)2-CH2-C(O)OEt + NaCl.