а) Cr --> CrCl3 --> Cr(OH)3 --> Cr(NO3)3
⬇️
K[Cr(OH)4]
2Cr + 6HCI -> 2CrCl3 + 3H2
CrCl3 + 3NaOH -> Cr(OH)3 + 3NaCl
Cr(OH)3 + KOH -> K[Cr(OH)4]
Cr(OH)3 + 3HNO3 -> Cr(NO3)3 + 3H2O
b) Cr2(SO4)3 --> Cr(OH)3 --> Cr2O3 --> Cr --> Cr2S3
Cr2(SO4)3 + 6KOH -> 3K2SO4 + 2Cr(OH)3
2Cr(OH)3 -(t°)-> Cr2O3 + 3H2O
Cr2O3 + 2Al -> Al2O3 + 2Cr
2Cr + 3S -> Cr2S3
c) Cr2(SO4)3 --> K2Cr2O7 --> K2CrO4--> BaCrO4
Cr2(SO4)3 + 2KMnO4 + 3H2O -> K2Cr2O7 + 2MnO2 + 3H2SO4
4K2Cr2O7 -(t°)-> 4K2CrO4 + 2Cr2O3 + 3O2
K2CrO4 + Ba(NO3)2 -> BaCrO4 + 2KNO3
Валентность меди равна 2